Painted Rock Mountains (dacite/trachydacite obsidian)

            This source in southwest Maricopa County, Arizona was not included in the discussion in 2005 since it had not yet been recovered in archaeological context (Shackley 2005).  A long-term project in western Arizona focused on the Patayan and Hohokam of western Arizona by Aaron Wright of Archaeology Southwest indeed recovered Painted Rock Mountains obsidian (Shackley 2021; Wright and Hopkins 2016).  In the 1990s four samples of very small marekanites were submitted by a CRM company from near the spillway of the dam, and in 2023 Archaeology Southwest submitted another sample from the same area.

            In December 2024, Aaron Wright, Chris Loendorf and I examined an area to the northwest of Painted Rock Reservoir dam where Wright recovered samples a few years earlier.  Very small marekanites (all ≤ 21 mm in diameter) were recovered within and eroding from a platy volcanic flow mapped by Skotnicki (1993) as a dacite: “Hard, dense, platy dacite flows.  Typically maroon or gray…Forms the south side of the spillway…and forms laminated outcrops. Locally vitrophyric, such as the hill downstream from the dam.” (Skotnicki 1993).

            This accurately describes the environment from which marekanites were recovered both in-situ and eroding downhill from the dacite in 2024.  An analysis of a vitrophyric marekanite embedded in the dacite indicates that the matrix is a trachydacite to dacite as described by Skotnicki (1993; see figure herein below).  This is a rare obsidian produced not from rhyolite but by a somewhat high silica dacite/trachydacite (see Figure below).  Trachyte obsidian does occur rarely and his been recorded in Sonora, as well as Hawai’i on the Big Island (McCoy 2011; Shackley 2024).  Since the proportion of silica (SiO2) is relatively low (< 70 weight percent) although aluminum (Al2O3) is relatively high here (17-20 wt. percent), the marekanites are quite small (see Shackley 2005).  As discussed in Shackley (2005:10-15), silica and aluminum function as the glass formers and if H2O is relatively low (< 1 wt. percent), glass can form, however even if silica is too low, but in this case aluminum high, small marekanites can form.  While this is not a rhyolitic obsidian the Painted Rock Mountain obsidian is knappable as seen in the debitage in the Pioneer/Colonial Hohokam contexts nearby. Given the small marekanite size, it is not surprising that this source has not been detected any distance from the source.

 

Oxide values for the two trachydacite/dacite (samples 6 and 7), the basalt overlying the trachydacite (samples 8 and 9), two rhyolite (obsidian) standards NBS-278 and RGM-1 and recommended values.  See TAS plot below.

Sample Na2O MgO Al2O3 SiO2 P2O5 K2O CaO TiO2 V2O5 MnO Fe2O3
120824-6 3.52 1.50 17.07 66.84 0.05 4.80 1.34 0.57 0.02 0.47 3.37 99.55
120824-7 1.26 2.03 20.50 64.16 0.05 5.45 1.38 0.51 0.02 0.13 4.06 99.56
120824-8 3.49 6.99 17.26 50.75 0.31 1.00 9.42 1.59 0.04 0.14 8.82 99.81
120824-9 3.14 5.32 17.54 52.13 0.34 1.06 10.76 1.33 0.03 0.13 8.01 99.80
NBS-278 4.49 0.02 14.01 73.25 0.01 4.40 1.01 0.23 0.01 0.06 2.28 99.76
NBS-278 rec. 4.84 0.23 14.15 72.97 0.04 4.16 0.98 0.25 nr 0.05 2.04  
RGM-1 3.83 0.02 13.76 74.01 0.01 4.57 1.23 0.24 0.00 0.04 2.05 99.77
RGM-1 rec. 4.07 0.28 13.70 73.40 nr 4.30 1.15 0.27 nr 0.04 1.86  

nr = not reported

 

TAS plot of the Painted Rock Mountain rocks recovered at the collection locality, and the two rhyolite (obsidian) standards NBS-278 and RGM-1.  Sample 120824-6 is a trachydacite matrix with an embedded vitrophyric obsidian marekanite, possibly yielding the slightly higher silica than another rock sample in the same area sample 120824-7.  The basalt and basaltic andesite is from the overlying later rock as mapped by Skotnicki (1993), his Tb unit as a “mesa capping flow”.

 

Elemental concentrations for the Painted Rock Mountains trachydacite obsidian, analysis of rhyolite (obsidian) standards NBS-278 and RGM-1 and recommended values.  "PR" samples are from earlier collections, and "120824" samples from the 2024 collection.

 

Sample Ti Mn Fe Rb Sr Y Zr Nb Ba Ce Pb Th
ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm
PR1 2016 292 14993 105 144 27 328 16 1677 81 18 13
PR2 2555 360 18566 98 154 29 339 18 1393 30 26 14
PR3 2613 371 18799 80 156 28 336 18 1325 85 25 15
PR4 2839 379 18832 82 154 30 328 17 1328 63 25 15
PR5 2695 394 19999 96 162 31 349 18 1427 60 26 13
120824-12 2150 313 15634 103 142 27 324 16 1673 66 20 10
120824-13 2071 316 15265 93 137 27 319 15 1709 61 16 11
120824-14 1986 297 14729 103 142 29 329 16 1653 83 19 9
120824-15 1985 303 14747 103 140 28 324 17 1707 76 20 10
120824-16 2799 398 19989 128 165 29 356 18 1595 47 28 15
120824-17 2239 313 15856 98 144 28 323 17 1654 64 19 13
120824-18 2506 358 17963 89 155 29 338 17 1407 68 26 14
120824-19 2278 357 16931 102 151 30 337 16 1576 62 21 14
RGM1-S4 1582 282 12335 141 102 26 226 10 817 32 27 16
RGM-1 rec. 1619 279 12995 150 110 25 220 9 810 47 24 15
NBS-278 1566 362 14158 125 59 43 299 19 1003 56 22 14
NBS-278 rec. 1469 403 14269 128 63 39 290 18 1140 62 16 12

 

Painted Rocks Mountains obsidian mean and central tendency from the data in table above (121224 analysis)

 

 

N

Minimum

Maximum

Mean

Std. Deviation

Ti

13

1985

2839

2364

317

Mn

13

292

398

342

38

Fe

13

14729

19999

17100

2005

Rb

13

80

128

98

12

Sr

13

137

165

150

9

Y

13

27

31

29

1

Zr

13

319

356

333

11

Nb

13

15

18

17

1

Ba

13

1325

1709

1548

149

Ce

13

30

85

65

15

Pb

13

16

28

22

4

Th

13

9

15

13

2

 

 

Collection localities in the Painted Rock Mountains

 

 

REFERENCES

McCoy, M.D.

2011 Geochemical Characterization of Volcanic Glass from Pu‘u Wa‘awa‘a, Hawaii Island. Rapa Nui Journal 25:41–49.

Shackley, M.S.

2021 Source Provenance of Obsidian Artifacts from a number of Hohokam and Patayan Contexts in Western Arizona.  Report prepared for Aaron Wright, Archaeology Southwest, Tucson, Arizona.

            2005  Obsidian: Geology and Archaeology in the North American Southwest.  University of Arizona.20

2024 Obsidian Sources and Source Provenance of Archaeological Obsidian in northern Sonora: the Known and Unknown.  In Reframing and Expanding Sonoran Archaeology, edited by H. M. Claypatch and E. Villalpando Canchola, Kiva 90:293-305.

Skotnicki, S.

1993 Geologic Map of the Painted Rock Mountains, Maricopa County, Arizona.  Open-File Report 93-7, Arizona Geological Survey.

Wright, A.M. and M.P. Hopkins

2016  The Great Bend of the Gila: Contemporary Native American Connections to an Ancestral Landscape.  Archaeology Southwest Technical Report 2016-101.  Tucson, Arizona.

 

 

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